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1、ISSN1023-1935,RussianJournalofElectrochemistry,2007,Vol.43,No.11,pp.1223–1228.©PleiadesPublishing,Ltd.2007.OriginalRussianText©Yu.G.Budnikova,T.V.Gryaznova,S.A.Krasnov,I.M.Magdeev,O.G.Sinyashin,2007,publishedinElektrokhimiya,2007,Vol.43,No.11,pp.1291–1296.Designof
2、EcologicallySafeandScienceIntensiveElectrochemicalProcesses1Yu.G.Budnikovaz,T.V.Gryaznova,S.A.Krasnov,I.M.Magdeev,andO.G.SinyashinArbuzovInstituteofOrganicandPhysicalChemistry,KazanScientificCenter,Kazan,RussiaReceivedDecember29,2006Abstract—Thisreviewdiscussesther
3、esultsofandprospectsforstudiesaimedatdesignofnewscienceinten-sive,environmentallysafetechnologiesforthesynthesisoforganophosphoruscompoundsbyhalogenationofα-olefins,includingmodificationofrapeseedoil;italsoconsidersmethodsfortheproductionofsomeotherintermediatesfo
4、rchemicalindustry.Newsyntheticapplicationshavebeendeveloped,usingcombinedmethodsofclassicalorganicchemistryandelectrochemistry,forprocessesbasedonelectrochemicalgenerationofcat-alysts(mediators)—complexesofmetalsinlowoxidationstates,halogencomplexes,etc.Selectivee
5、lectro-chemicalproceduresaresuggestedforthesynthesisoftriphenylphosphine,trialkylphosphates,andnanosizedtransitionmetalphosphidesfromwhitephosphorus.Keywords:electrosynthesis,chemicaltechnology,olefins,chloroparaffins,whitephosphorus,metalphos-phidesDOI:10.1134/S102
6、3193507110018INTRODUCTIONradicallynewapproachthatsatisfiestherigidecologi-calrequirementstomodernchemistry.Developmentofscienceintensive,resource-saving,andenvironmentallycleantechnologiesaimedatexportofhigh-technologyproductsiscurrentlyoneofElectrochemicalHalogena
7、tionofUnsaturatedthemajorstrategiesinscienceandtechnology.Electro-CompoundsinProductsofPetrochemicalSynthesischemicaltechnologiesprovidemildconditionsofandRapeseedOilchemicaltransformationsandminimumuseoftoxicandfire-hazardousreagents,andleadtominimumModernchemical
8、industryhasincreasingdemandinwasteinproductionprocesses.Sinceoxidationandproductswithlong-chainhydrocarbonradicals(ë16andreductionareconductedwithoutche
