资源描述:
《DL-异柠檬酸-γ-内酯降解杉木铝毒害的作用机理分析》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、捐建农林大学二00七届硕士学位论文部总铝含量是茎部的几十倍以上,这也说明根部是铝对杉木幼苗害毒的最初部位.仅在铝胁迫45d时在根中检羽倒含量很低的铝络合物,铝络台物是直接进入植物体内,还是进入体内的~。与伴内已经存在的DL-异柠檬酸吖.内酯作用还需要进一步研究.经过铡定,培养液中DL-异柠檬酸吖.内酯浓度未见明显变化,估计进入植物体内的络合物含量少于0.0002%,而培养液中铝在DL-异柠檬酸千内酯存在条件下约70%络合物形式存在.由此可见,与铝络合形成难以被植株体吸收的络合物可能是DL-异柠檬酸吖-内
2、酯降低活性铝对杉木幼苗毒害作用的主要机制.8、通过红外吸收光谱法和核磁共振技术进一步对DL-异柠檬酸吖.内酯与铝的络合物的结构进行鉴定,发现是2个DL-异柠檬酸一y.内酯失去羟基上的氢与1个AI“与形成较稳定络合物.关键词:杉木;铝毒害:DL-异柠檬酸一Y一内酯;络合物;降解机理ⅢDL一异拧檬酸一Y一内酯降解杉木铝毒害的作用机理研究MechanismsofAluminumDetoxificationinChineseFirbyDL·-hydroxy-1,2,3··proanetracarboxylicA
3、bstractTheocnbinedinfluenceofthepHvalue,theconcentrationofactive,At,theconcentralionofDL-hydtoxy-1,2,3-proanetracurboxylicandthenutritionlevelonthe1year'Chinese矗rsee&rigoRtheAIabsorptionwe站studicdbyI姐kfanningexperimentsUsingfegressiverelationdesign.Aseri
4、esofthequadi'aficequationsoffernfactorsWeTcolHimlzedandsettedupbymsaauringthetot暑Iaminopheno
5、,activealuminumconcentration,electricalconductivity,pHvalue,theconcentrmionofDL-hydroxy-1,2,3-pmanetracurhexylic,theConcentrationofaluminumcoordinationcompoundin
6、theculturalsolutionandthetotalaluminumandaluminumcoordinationcompoundinthedifferentorgansofChinesefirseedingatdifferentaluminumstress删ods(theearlyperiod.'0-15days,themediumpedod:16-30daD,thefinalpeliod"3145days),andwlththev耐an∞analysisof醴耶dufal删fixofIhel
7、b啦faclorsandtheconeimioncoe伍ciem,theparametersoftheestablishedmathematicalmodelwegeoptimlze,LTheIe印ondingo.ilveoftheindexeswase5labliashedwiththedIangcsofthefourfactorsaccordingtotheestabfishedmathematicalmodels,Thestructureofthecourdimtioncompoundofahtn
8、面numandDL-hyd∞oxy·1,2,3-pmanetracarboxylicw∞identifiedbyIRandl婚techniques.Theaimofthispaper王_tryingtofindthefurtheftheoreticalExplainationofthcdegradingAItoxicitymechanismofDL-hydmxy-1,2,3-proanettacatboxylicgoChinesefir.Theresultsshowed:1知theconcentrati
9、on0facliveAIincreasingandtheperiodofAIstresspostpomn吕thetotalamlnophenolconoentrmionintheculturalsoIntionincreasedasawhole.whenthepHvalue,theconcentrationofactiveAI.andnutritionconcentrationinthesolutiⅡweiedecided,thetotal