最新31P的化学位移表.doc

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1、精品资料31P的化学位移表........................................精品资料31PChemicalShiftsIfyouhavemeasureda31Pchemicalshiftand/orcouplingconstantthatdoesnotappearinthetablesbelow,andyouwouldlikeyourmeasurementtobeincludedhere,contactthe.Phosphorous(III)ChemicalShiftTable(fromBrukerAlmanac1991)C

2、ompoundChemicalShift(ppm) Relativeto85%H3PO4PMe3-62PEt3-20PPr(n)3-33PPr(i)3+19.4PBu(n)3-32.5PBu(i)3-45.3PBu(s)3+7.9PBu(t)3+63PMeF2245........................................精品资料PMeH2-163.5PMeCl2+192PMeBr2+184PMe2F+186PMe2H-99PMe2Cl-96.5PMe2Br-90.5Phosphorous(V)ChemicalShiftTable(

3、fromBrukerAlmanac1991)CompoundChemicalShift(ppm) Relativeto85%H3PO4Me3PO+36.2Et3PO+48.3[Me4P]+1+24.4[PO4]-3+6.0PF5-80.3PCl5-80MePF4-29.9-158........................................精品资料Me3PF2Me3PS+59.1Et3PS+54.5[Et4p]+1+40.1[PS4]-3+87[PF6]-1-145[PCl4]+1+86[PCl6]-1-295Me2PF3+8.0...

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