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1、PhaseEquilibria,PhaseDiagramsandPhaseTransformationsSecondEditionThermodynamicprinciplesarecentraltounderstandingmaterialbehaviour,particularlyastheapplicationoftheseconceptsunderpinsphaseequilibrium,transformationandstate.Whilethisisacomplexandchallengingarea,theuseofcomputationaltoolshasallowe
2、dthematerialsscientisttomodelandanalyseincreasinglyconvolutedsystemsmorereadily.Inordertouseandinterpretsuchmodelsandcomputedresultsaccurately,astrongunderstandingofthebasicthermodynamicsisrequired.Thisfullyrevisedandupdatededitioncoversthefundamentalsofthermodynamics,withaviewtomoderncomputerap
3、plications.Thetheoreticalbasisofchemicalequilibriaandchemicalchangesiscoveredwithanemphasisonthepropertiesofphasediagrams.Startingwiththebasicprinciples,discussionmovestosystemsinvolvingmultiplephases.Newchapterscoverirreversiblethermodynamics,extremumprinciplesandthethermo-dynamicsofsurfacesand
4、interfaces.Theoreticaldescriptionsofequilibriumconditions,thestateofsystemsatequilibriumandthechangesasequilibriumisreached,arealldemonstratedgraphically.Withillustrativeexamples–manycomputercalculated–andexerciseswithsolutions,thistextbookisavaluableresourceforadvancedundergraduateandgraduatest
5、udentsinmaterialsscienceandengineering.Additionalinformationonthistitle,includingfurtherexercisesandsolutions,isavail-ableatwww.cambridge.org/9780521853514.Thecommercialthermodynamicpackage‘Thermo-Calc’isusedthroughoutthebookforcomputerapplications;alinktoalimitedfreeofchargeversioncanbefoundatt
6、heabovewebsiteandcanbeusedtosolvethefurtherexercises.Inprinciple,however,asimilarthermodynamicpackagecanbeused.MHisaProfessorEmeritusatKTH(RoyalInstituteofTechnology)inStockholm.PhaseEquilibria,PhaseDiagramsandPhaseTransformationsTheirThermodynamicBasisSecondEditionMATSHILLERTDepartment
7、ofMaterialsScienceandEngineeringKTH,StockholmCAMBRIDGEUNIVERSITYPRESSCambridge,NewYork,Melbourne,Madrid,CapeTown,Singapore,SãoPauloCambridgeUniversityPressTheEdinburghBuilding,CambridgeCB28RU,UKPublishedintheUnitedStatesofAm