含苯氧基、联萘氧基、偶氮苯氧基均三嗪衍生物制备和表征

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1、福建师范大学硕士学位论文摘要AbstractInthispaper,cyanuricchloridewhichs缸uc嘶containingthreechlorineatomswasusedasthemainrawmaterialfortheprovisionofs-triazinering．Wahthedifferentreactivitiesofthethreechlo血eatomsincyanuricchloride，aseriesofnews．triazineringcompoundswerereceivedbythestep-wisereactionthr

2、oughthecontrollingofthetemperature．Thes觚ctureofthesecompoundswerecharacterizedbyElementalanalysis，IR，1HNMRandotherresearchmethods，alsothesolubility,thermalstabilitypropertieswerestudied．Itcanbesummarizedasfollows．1．Withcyanuricchlorideandp-nitrophenolastherawmaterials，2,4，6-3-p—nitroph

3、enoxy-1，3，5-triazineWaspreparedbycontrollingofreactiontemperatureinacetoneandwater．Threedifferentmethodswereusedfornitroreductiontoobtain2,4，6．一aminophenoxy-1，3，5一triazine．Withelementalanalysis，1H-NMR,IR,TGcharacterizationtheproductsobtained，2,4，6—3-P—nitrophenoxy-1，3，5一tfiazineshowsgo

4、odthermalstabilitywhichtheinitialdecompositiontemperaturewasat430"C．Pd／12hydrazinecatalystsystemshowsagoodresultinthreekindsofreductionmethods．2．Witheyanuricchlorideand1，1’BINOLastherawmaterials，NaOHasbase，cetyltrimethylammoniumbromideasphasetransfercatalyst,poly2-chloro-4—1，l’-binapht

5、hyloxy-1，3，5-triazinewerepreparedthroughinterracialpolymerization．Itsstructurewascharacterizedusinguv,IR,1H—NMR,RF,GPC．Alsobyatomicforcemicroscope(AFM)，thesurfaceofthepolymerfilmWasobserved．3．PCCABwasabtainedbythereactionofcyanuricchlorideand4，4’-hydroxyazobenzeneusinginterfacialpolyme

6、rization．DIATOBw豳gotbythereactionof2-Anilino·4，6一dicholoride·1，3，5一traizineand4,4'-hydroxyazobenzeneat40"CinthesolventofacetoneandWater．FTIR,1HNMR,TGDSC，UVwereusedtocharacterizethestructures．AndtheopticlresponsepropertyofDIATOBWasstudiedbyUV二Ⅵs．Alsothesolubilityofthetwoproductswerestud

7、ied，PCCABwon’tdissolveeveniIlDMF，butDIATOBcanbedissolvedinmostkindsofsolvent．III■-L●。；●J福建师范大学硕士学位论文Keywords：Cyanuricchloride,dendrimer,binaphthol，azobenzene，interracialpolymerization，functionalmaterials，s·triazinederivativesIV^中文文摘三聚氯氰具有特殊的结构和反应特性，与三嗪环相连的3个氯原子具有不同的反应活性，可在不同的反应温度及pH下