Chemical Thermodynamics英文文献资料

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1、1LeoLueChemicalThermodynamicsDownloadfreebooksatBookBooN.com2ChemicalThermodynamics©2009LeoLue&VentusPublishingApSISBN978-87-7681-497-7DownloadfreebooksatBookBooN.com3ChemicalThermodynamicsContentsContents1Introduction81.1Basicconcepts81.1.1Statefunctionversuspathfunction81.1.2Intensivep

2、ropertyversusextensiveproperty81.2Briefreviewofthermodynamics81.2.1Thefirstlawofthermodynamics81.2.2Thesecondlawofthermodynamics91.3Thefundamentalequationofthermodynamics91.4Thecalculusofthermodynamics111.5Opensystems131.6Legendretransformsandfreeenergies142Singlecomponentsystems172.1Gene

3、ralphasebehavior172.2Conditionsforphaseequilibrium182.3TheClapeyronequation20what‘smissinginthisequation?YoucouldbeoneofourfuturetalentsPleaseclicktheadvertmaeRsKinteRnationaLteChnoLogY&sCienCePRogRammeAreyouabouttograduateasanengineerorgeoscientist?Orhaveyoualreadygraduated?Ifso,therema

4、ybeanexcitingfutureforyouwithA.P.Moller-Maersk.www.maersk.com/mitasDownloadfreebooksatBookBooN.com4ChemicalThermodynamicsContents3Multicomponentsystems223.1Thermodynamicsofmulticomponentsystems223.1.1Thefundamentalequationofthermodynamics223.1.2Phaseequilibria223.1.3Gibbsphaserule233.2Bi

5、narymixtures253.2.1Vapor-liquidequilibrium253.2.2Liquid-liquidequilibria303.2.3Vapor-liquid-liquidequilibria313.3Ternarymixtures344Theidealsolutionmodel364.1Definitionoftheidealsolutionmodel364.2DerivationofRaoult’slaw375Partialmolarproperties405.1Definition405.2Relationshipbetweentotalpro

6、pertiesandpartialmolarproperties415.3Propertieschangesonmixing435.4Graphicalrepresentationforbinarysystems43www.job.oticon.dkDownloadfreebooksatBookBooN.com5ChemicalThermodynamicsContents6Nonidealsolutions476.1DeviationsfromRaoult’slawandtheactivitycoefficient476.2ModifiedRaoult’slaw486.3E

7、mpiricalactivitycoefficientmodels516.4TheGibbs-Duhemequation526.5Azeotropicsystems537Stability567.1Introduction567.2Liquid-liquidequilibrium608Solid-liquidequilibrium628.1Introduction628.2Phasebehavior628.3Conditionsforequilibrium629GassolubilityandHenry’slaw669.1Henry’sla