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1、攀枝花学院本科毕业论文酸改性粉煤灰吸附除磷性能研究学生姓名:王硕学生学号:200810903031院(系):生物与化学工程学院年级专业:2008级环境工程指导教师:陈孝娥讲师助理指导教师:二O—二年六月我国是个产煤大国,以煤炭为电力生产基本燃料。近年来,粉煤灰的排放量急剧增加,而粉煤灰的综合利用率很低,人量的粉煤灰不仅造成堆积,片用大量土地,而且造成环境的极大破坏,粉煤灰的综合利用迫在眉睫。排入地表水体的磷酸盐是引起水体富营养化的主要因素之一,因此,废水排放时磷的含量需达到国家规定的标准。含磷废水达标排放一般进行深度处理,粉煤
2、灰直接用来处理含磷废水效果不理想。为进一步提高粉煤灰的吸附性能,尝试用酸对粉煤灰改性。本论文对酸改性粉煤灰吸附除磷性能进行了研究,探究了磷的初始浓度,改性粉煤灰的投加量,反应时间,反应温度,焙烧温度和PH值对吸附效果的影响。实验结果表明:在相同的实验条件下,酸改性粉煤灰对磷的去除率都要好于未改性粉煤灰对磷的去除率。对50mg/L含磷废水,酸改性粉煤灰的投加量为1.5g时去除率为95.62%,吸附时间50分钟时去除率为95.32%,反应温度常温时去除率为94.42%,焙烧温度100°C时去除率为94.33%,PH+性时去除率为9
3、2.18%。关键词酸改性,粉煤灰,吸附,含磷废水ABSTRACTChinawasalargecoal-producingcountry,thebasicfuelofcoalforelectricityproduction.Inrecentyears,flyashemissionssharplyincreased,andthecomprehensiveutilizationofflyashwasverylow,andalotofflyashnotonlycausedbytheaccumulation,andalotoflandb
4、eentakeup,andcausedgreatdamagetotheenvironment,socomprehensiveutilizationofflyashbecameimminent.Dischargedintosurfacewaterbodies,phosphatewasoneofthemainfactorsthatcausedeutrophication,therefore,thecontentofphosphorusinthewastewaterdischargeneededtoreachthestatestan
5、dards.Phosphoruswastewaterdischargestandardsgenerallydepthtreatmentofflyashdirectlytodealwiththephosphorus-containingwastewatertheresultwasnotideaLTofurtherenhancetheadsorptionpropertiesofflyash,wetriedtomodifyflyashwithacid.Inthisthesis,discussedtheremovalofacid-mo
6、difiedflyashadsorbphosphorus,exploredtheeffectofthephosphorusconcentrationoftheinitialdosageofmodifiedflyash,mixingtime,reactiontemperature,calcinationtemperatureandPHoftheadsorption.experimentalresultsshowthat:onthesameexperimentalconditions,theacid-modifiedflyasho
7、ntheremovalrateofphosphorusshouldbebetterthantheunmodifiedflyashontheremovalrateofphosphorus.The50mg/Lphosphorous-containingwastewater,acidmodifiedflyashdosagewas1.5gwhenremovalratewas95.62%,theadsorptiontimeof50minutesduringremovalratewas95.32%,reactiontemperaturew
8、asroomtemperaturewhenremovalratewas94.42%,theroastingtemperature100centigraderemovalratewas94.33%.PHwasneutralwhentheremovalratewas92.18%.