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1、SupportingInformationFacet-DependentandAdjacentFacet-RelatedElectricalConductivityPropertiesofSrTiO3CrystalsPei-LunHsieh,†,§MaheshMadasu,‡,§Chien-HsuanHsiao,‡,§Yun-WenPeng,‡,§Lih-JuannChen,,†,§andMichaelH.Huang,‡,§†DepartmentofMaterialsScienceandEngineering,‡DepartmentofChemistry,and§Fro
2、ntierResearchCenteronFundamentalandAppliedSciencesofMatters,TsingHuaUniversity,Hsinchu30013,TaiwanSynthesisofCu2ORhombicuboctahedra.First,2.9948gofcopperacetateand75mLofdeionizedwaterwereaddedintoabeakerandkeptat70°C.Next,3.6gofNaOHdissolvedin10mLofdeionizedwaterwasintroducedandstirredfo
3、r5min,followedbytheadditionof0.6gofD-(+)-glucosewithstirringfor40min.Afterthereactionwiththesolutionreturningtoroomtemperature,thesolutionwascentrifugedat5000rpmfor5minandwashedwith40mLof1:1volumeratioofwaterandethanolthreetimes.Finally,Cu2Ocrystalsweredispersedin99%ethanolsolution.Probe
4、Preparation.First,astraighttungstenwirewithadiameterof0.5mm(99.95%,StremChemicalsInc.)wascutintopieces,dippedintoa2.0MNaOHelectrolytesolution,andappliedacurrentof1Aat15Vtosharpenthetips.Thetipswereimmersedina10MNaOHsolutionfor5sectoremovesurfacetungstenoxidelayer,followedbydeionizedwater
5、cleaning.Thetipdiameterisabout100nm.TiCl4WaterEthanolLiOHSrCl2·6H2OTemperatureTimeCubes26μL2.5mL1mL3.7mL(3M)0.07g70°C3hEthyleneTiCl4WaterHexanolLiOHSrCl2·6H2OTemperatureTimeGlycolTruncatedRhombicDodecahedra26μL40mL0.5mL0.7mL3.7mL(3M)0.07g200°C20hStir5minStir30minTiCl4/SrCl2·6H2OLiOHHeatV
6、ialinautoclaveH2O+partiallyfilledEG/hexanol/ethanolicebathwithwaterFigureS1.ReagentamountsandthereactionconditionusedforthegrowthofSrTiO3cubesand{100}-truncatedrhombicdodecahedra.S1a8b600c2000{100}to{100}{110}to{110}{110}to{110}61500400410002002500)))A0An0An0n(((III-2-500-200-4-1000-400-
7、6-1500{100}to{100}{110}to{110}{110}to{110}-8-600-2000-20-15-10-505101520-6-4-20246-6-4-20246V(V)V(V)V(V)d50e50f{100}to{100}{100}to{100}1000{100}to{110}4040800303060020204001010200)))A0A0A0n(-10(nn(-200II-10I-20-20-400-30-30-600-800-40{100}to{100}-40{110}to{100}{100}to{100