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1、AdvancedOrganicChemistryFIFTHEDITIONPartB:ReactionsandSynthesisAdvancedOrganicChemistryPARTA:StructureandMechanismsPARTB:ReactionsandSynthesisAdvancedOrganicFIFTHChemistryEDITIONPartB:ReactionsandSynthesisFRANCISA.CAREYandRICHARDJ.SUNDBERGUniversityofVirginiaCharlott
2、esville,VirginiaFrancisA.CareyRichardJ.SundbergDepartmentofChemistryDepartmentofChemistryUniversityofVirginiaUniversityofVirginiaCharlottesville,VA22904Charlottesville,VA22904LibraryofCongressControlNumber:2006939782ISBN-13:978-0-387-68350-8(hardcover)e-ISBN-13:978-0
3、-387-44899-2ISBN-13:978-0-387-68354-6(softcover)Printedonacid-freepaper.©2007SpringerScience+BusinessMedia,LLCAllrightsreserved.Thisworkmaynotbetranslatedorcopiedinwholeorinpartwithoutthewrittenpermissionofthepublisher(SpringerScience+BusinessMedia,LLC,233SpringStree
4、t,NewYork,NY10013,USA),exceptforbriefexcerptsinconnectionwithreviewsorscholarlyanalysis.Useinconnectionwithanyformofinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilarmethodologynowknoworhereafterdevelopedisforbidden.Theuseint
5、hispublicationoftradenames,trademarks,servicemarksandsimilarterms,eveniftheyarenotidentifiedassuch,isnottobetakenasanexpressionofopinionastowhetherornottheyaresubjecttoproprietaryrights.987654321springer.comPrefaceThemethodsoforganicsynthesishavecontinuedtoadvancerap
6、idlyandwehavemadeanefforttoreflectthoseadvancesinthisFifthEdition.Amongthebroadareasthathaveseenmajordevelopmentsareenantioselectivereactionsandtransitionmetalcatalysis.Computationalchemistryishavinganexpandingimpactonsyntheticchemistrybyevaluatingtheenergyprofilesof
7、mechanismsandprovidingstructuralrepresentationofunobservableintermediatesandtransitionstates.TheorganizationofPartBissimilartothatintheearliereditions,butafewchangeshavebeenmade.ThesectiononintroductionandremovalofprotectinggroupshasbeenmovedforwardtoChapter3tofacili
8、tateconsiderationofprotectinggroupsthroughouttheremainderofthetext.EnolateconjugateadditionhasbeenmovedfromChapter1toChapter2,where
