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1、齐齐哈尔大学毕业设计（论文）题口11」钩钻杂多酸掺杂材料制备及光降解催化性能研究学院专业班级化学101学生姓名XXX指导教师单秋杰成绩2014年6}]H齐齐哈尔大学毕业设计(设计)摘要木论文采用的直接法合成了两个杂多酸盐，结构是Keggin类型K8[Ni(H2O)WiiCoO39]和K8[Zn(H2O)W]iCoWiiO39]，利用这两种盐与PANI反应合成了聚苯胺掺杂的多金属杂多酸盐掺杂材料通过化学氧化还原法K8[Ni(H2O)W1iCoO39]/PANI>K8[Zn(H2O)Wi!CoO39]/PANI,并用IR、XRD、UV等对制备出的样品进
2、行了表征。此外，以所合成的掺杂材料为催化剂，在紫外灯下照射lOOmin,研究了孔雀石绿溶液的光催化降解的反应。实验研究结果表明，两种杂多酸盐掺杂材料的光降解的最佳条件一致，当孔雀石绿溶液以5mg/L为最初的浓度、加入O.O8g的合成的催化剂、pH=2时，催化脱色效果最佳。此时，当催化剂为K8[Zn(H2O)W!!CoO39]/PANI时，孔雀石绿染料液脱色效果是85.30%；当催化剂为K8[Ni(H2O)WiiCoO39]/PANI时，孔雀石绿染料液脱色率是89.92%；当催化剂为K8[Zn(H2O)WnCoO39]时，孔雀石绿溶液脱色率为48.7
3、3%；当催化剂为K8[Ni(H2O)W11CoO39]时，孔雀石绿溶液脱色率为55.63%；当没有催化剂时，孔雀石绿口动降解溶液脱色率22.97%0PANI和杂多酸盐掺杂后所制备出的催化剂具有非常好催化活性。关键词:杂多酸盐；Keggin；聚苯胺；掺杂;光催化；孔雀石绿；降解AbstractInthiswork,TwoheteropolyacidsaltsaresynthesizedbythedirectmethodKg[Ni(H20)W11COO39],Ks[Zn(H2O)W11COO39]andthestructureofeverysaltis
4、Keggin.ThematerialsthatthetwosailtsdopedpolyanilinearesynthesizedbythewayofchemicaloxidationmethodK8[Ni(H2O)Wi1CoO39]/PANI,K8[Zn(H2O)Wi1CoO39]/PANLAndallofthemarecaterizedthoroughlybyUV,IRandXRD.Inaddition,photocatalyticdegradationreactionofmalachitegreensolutioninthesametimei
5、nwhichthesynthesizedmateriasarecatalysts,isstudiedundertheUVlightlOOmin.Afterthetest,theresultshaveshownthatastheinitialconcentrationofthemalachitegreensolution5mg/L,thedosageofthecatalyst0.08g,thesolutionpH=2,therateofthecatalyticdecoloringreactionisthehightest.Atthispoint,as
6、toKg[Zn(H20)WiiCoO39]/PANIasthecatalyst,themalachitegreensolutiondecolorizationratecanreach85.30%；AsthecatalystfortheK8[Ni(H2O)WnCoO39]/PANI,themalachitegreensolution5mg/Ldecoloringrateis89.92%;WhenthecatalystfortheKs[Zn(H2O)W11COO39],therateofthedecolorizationreactionis48.73%
7、;AsthecatalystfortheKs[Ni(H2O)W11COO39],thedecolorizationrateofthe5mg/Lmalachitegreensolutionis55.63%;Thedegradabilityreactionrateofthesamesolutionbutwithoutcatalystis22.97%.TheperformanceofthepolyanilinedopedwithheteropolyacidsaltcatalystKs[Ni(H2O)W11CoO39]/PANIinthesolutioni
8、sbest.Keywords:Heteropolyacidsalt;Keggin;Polyaniline;Doping;P
