Electrodialytic removal of fluoride from water Effects of process parameters

Electrodialytic removal of fluoride from water Effects of process parameters

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时间:2019-03-01

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1、SeparationandPurificationTechnology64(2008)147–153ContentslistsavailableatScienceDirectSeparationandPurificationTechnologyjournalhomepage:www.elsevier.com/locate/seppurElectrodialyticremovaloffluoridefromwater:EffectsofprocessparametersandaccompanyinganionsErdemErgun

2、a,AliTora,∗,YunusCengeloglub,IzzetKocakbaSelcukUniversity,DepartmentofEnvironmentalEngineering,Campus,42031Konya,TurkeybSelcukUniversity,DepartmentofChemistry,Campus,42031Konya,TurkeyarticleinfoabstractArticlehistory:Theremovaloffluoridefromwaterbyusingelectrodialy

3、siswithSB-6407anionexchangemembranewasReceived29January2008testedatdifferentcurrentdensities.AfterthedeterminationoftheoptimumpHoffeedphaseunderDon-Accepted22September2008nandialysisconditionwhichgavethemaximumtransportoffluoride,theeffectofmono-andbi-valentions,su

4、chaschlorideandsulphate,inthefeedphaseontheremovalwasinvestigatedbyelectrodialysis.Keywords:ThetransportoffluoridewasalsocorrelatedwiththefluxdataandexplainedaccordingtostructureofFluoridemembrane.Itwasfoundthattheremovaloffluoridewashigherintheabsenceofmono-andbi-va

5、lentDefluoridationions.ThereducingeffectofsulphateionsonthetransportoffluoridewashigherthanthatofchlorideElectrodialysisions,whichwasexplainedbyconsideringinteractionofbothchlorideandsulphateionswiththeionicAnion-exchangemembranegroupinthemembraneandactivitycoefficie

6、ntoffluorideinthepresenceofmono-andbi-valentionset.Moreover,transportoffluorideincreasedwithincreasingcurrentdensityandfeedphaseconcentration.Asthedrivingion,thechlorideionismoreefficientthanthesulfateion.Applicationofelectrodialysiswascarriedoutontherealwatercontain

7、ing20.6mg/Loffluoride.Despitethepresenceofchlorideandsulphateinrealwatersample,fluorideconcentrationcouldbereducedto0.8mg/L(96%removal),whichwaslowerthanWorldHealthOrganization(WHO)standard(1.5mg/L).©2008ElsevierB.V.Allrightsreserved.1.Introductiongreatlyincreasedwh

8、entherearenocarbonregenerationunitslocally[18,19].Therefore,inrecentyears,differenttypesoflow-costFluorideindrinkingwatercanbeeitherbeneficialordetri-mat

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