[化学丛书].Modern.Inorganic.Chemistry

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1、ModerninorganicchemistryANINTERMEDIATETEXTC.CHAMBERS,B.Sc.,Ph.D.,A.R.I.C.SeniorChemistryMaster,BoltonSchoolA.K.HOLLIDAY,Ph.D.,D.Sc.,F.R.I.C.ProfessorofInorganicChemistry,TheUniversityofLiverpoolBUTTERWORTHSTHEBUTTERWORTHGROUPENGLANDButterworth&Co(Publishers)LtdLondon:88Kingsway,WC2B6ABAUSTRA

2、LIAButterworthsPtyLtdSydney:586PacificHighway,NSW2U67Melbourne:343LittleCollinsStreet3000Brisbane:240QueenStreet4000CANADAButterworth&Co(Canada)LtdToronto:2265MidlandAvenue,Scarborough,Ontario,M1P4SLNEWZEALANDButterworthsofNewZealandLtdWellington:26-28WaringTaylorStreet1SOUTHAFRICAButterwort

3、h&Co(SouthAfrica)(Pty)LtdDurban:152-154GaleStreetFirstpublished1975©Butterworth&Co(Publishers)Ltd1975PrintedandboundinGreatBritainbyR..).AcfordLtd.,IndustrialEstate,Chichester,Sussex.Contents1Theperiodictable12Structureandbonding253Energetics624Acidsandbases:oxidationandreduction845Hydrogen1

4、116GroupsIandII1197TheelementsofGroupIII1388GroupIV1609GroupV20610GroupVI25711GroupVII:thehalogens31012Thenoblegases35313Thetransitionelements35914TheelementsofGroupsIBandIIB42515Thelanthanidesandactinides440Index447PrefaceThewelcomechangesinGCEAdvancedlevelsyllabusesduringthelastfewyearshav

5、epromptedthewritingofthisnewInorganicChemistrywhichisintendedtoreplacethebookbyWoodandHolliday.Thisnewbook,likeitspredecessor,shouldalsobeofvalueinfirst-yeartertiarylevelchemistrycourses.Thenewsyllabuseshavemadeitpossibletogomuchfurtherinsystematisingandexplainingthefactsofinorganicchemistry

6、,andinthisbookthefirstfourchap-ters—-theperiodictable;structureandbonding;energetics:andacidsandbaseswithoxidationandreduction—providethenecessarygroundingforthelaterchaptersonthemaingroups,thefirsttransi-tionseriesandthelanthanidesandactinides.Althoughasimilaroveralltreatmenthasbeenadoptedi

7、nalltheselaterchapters,eachparticulargrouporserieshasbeentreateddistinctively,whereappropriate,toemphasisespecialcharacteristicsortrends.Amajordifficultyinaninorganictextistostrikeabalancebetweenashortreadablebookandalonger,moredetailedtextwhichcan