欢迎来到天天文库
浏览记录
ID:39963087
大小:402.50 KB
页数:13页
时间:2019-07-16
《cro制备方法中英文方法》由会员上传分享,免费在线阅读,更多相关内容在教育资源-天天文库。
1、PrimarychromiumproductionChromiumoresCrocoite(PbCrO4)Chromite(FeCr2O4;MgCr2O4)monocliniccrystalsystemisometriccrystalsystemIntroductionofChromiumoresCrocoiteCrocoiteisamineralconsistingofleadchromate,PbCrO4,andcrystallizinginthemonocliniccrystalsystem.Itiscommonlyfoundaslarge,well-devel
2、opedprismaticcrystals,althoughinmanycasesarepoorlyterminated.OnexposuretoUVlightsomeofthetranslucencyandbrilliancyislost.Chromiteistheonlyvaluableoreofchromiumtoproductchromium(III)oxide.Chromiteisanoxidemineralcomposedofchromium,ironandoxygen(FeCr2O4).Itisadarkgraytoblackincolorwithame
3、tallictosubmetalliclusterandahighspecificgravity.Itoccursinbasicandultrabasicigneousrocksandinthemetamorphicandsedimentaryrocksthatareproducedwhenchromite-bearingrocksarealteredbyheatorweathering.ChromiteCategoryColorCrystalsystemUnitcellMohsscalehardnessOpticalpropertiesCrocoiteOrange,
4、red,yellowMonoclinica=7.12Å,b=7.421Å,c=6.8Åβ=102.41°2.5-3Biaxial(+)ChromiteBlacktobrownishblackIsometrica=8.344ÅZ=85.5IsotropicIdentificationofChromateMineralsIndustrialproductionofCr2O3(solid-phasesynthesis)Intheindustryfieldsthegeneralproductionmethodissolid-phasereactionbycalciningCr
5、O3.Undertheconditionsof700℃and90minutes,when2%~3%ofthecombustiblepowderandtheadequatewaterwereadded,itshowedthatthesizeofCr2O3powderwasabout200nm.以铬酸酐热分解制备Cr2O3工艺为基础,在可燃性粉末质量分数2%~3%、适量水,温度为700℃,时间为90min的条件下,可得到平均粒径为200nm,分散性良好的Cr2O3微粒。Solid-phaseReactionProcess(thereactionprinciples)Cal
6、ciningCrO3:Theoverallreaction:4CrO32Cr2O3+3O2CrO3HCrO4removeinflammablepowderCr2O3Solid-phaseSynthesisProcess(preparation)IndustrialproductionofCr2O3(calciningchromiumhydroxide)Thesodiumchromatesolutionwasaddedsulfurtoreducehexavalentchromiumtotrivalentchromium,thenformingtheprecipitati
7、onofchromiumhydroxide.atlastgeneratingchromiumoxidebycalciningchromiumhydroxide.氢氧化铬法:将铬酸钠溶液加入硫磺还原铬酸钠溶液,使铬从六价还原成三价从而形成氢氧化铬沉淀,然后煅烧脱水变成氧化铬。反应式:4Na2CrO4+6S+7H2O=4Cr(OH)3↓+3Na2S2O3+2NaOH2Cr(OH)3=Cr2O3+3H2OCalciningchromiumhydroxide(preparation)破碎机硫磺块球磨机水或上液层反应罐铬酸钠溶液蒸汽水管式过滤器上层液制硫代
此文档下载收益归作者所有