Chapter 20-Electrochemistry of Organosilicon Compounds (p 1187-1232)

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1、TheChemistryofOrganicSiliconCompounds.Volume2EditedbyZviRappoportandYitzhakApeloigCopyright¶1998JohnWiley&Sons,Ltd.ISBN:0-471-96757-2CHAPTER20ElectrochemistryoforganosiliconcompoundsTOSHIOFUCHIGAMIDepartmentofElectrochemistry,TokyoInstituteofTechnology,Midori-ku,Yo

2、kohama226,JapanFax:81-45-921-1089;e-mail:fuchi@echem.titech.ac.jpI.INTRODUCTION....................................1188II.ANODICOXIDATIONOFORGANOSILICONCOMPOUNDS.....1188A.Alkylsilanes......................................1188B.Arylsilanes..........................

3、............1189C.Benzylsilanes,AllylsilanesandRelatedCompounds...........1190D.OrganosiliconCompoundsBearingHeteroatoms..............11961.Organosiliconcompoundsbearingsulfur.................11972.Organosiliconcompoundsbearingnitrogen...............11993.Organosil

4、iconcompoundsbearingphosphorus.............12014.Organosiliconcompoundsbearingoxygen................1201E.Acylsilanes......................................1203F.SilylEnolEthersandRelatedCompounds..................1204G.CarboxylicAcidBearingaˇ-TrimethylsilylGroup...

5、.........1206H.OrganosiliconCompoundsHavingSi
SiBondsandRelatedCompounds......................................1207I.Hydrosilanes.....................................1208J.HeterocyclesContainingaSiAtom......................1210III.CATHODICREDUCTIONOFORGANOSILICONCOM

6、POUNDS...1211A.Arylsilanes......................................1211B.Acylsilanes......................................1212C.Polysilanes......................................1212D.Halosilanes......................................12141.Cathodicreductionofhalosilanes

7、......................12142.Cathodicreductionofhalomethylsilanes.................12183.Utilizationaselectrophiles..........................1220E.Hydrosilanes.....................................1229IV.ACKNOWLEDGMENT................................1229V.REFERENCES..

8、....................................122911871188ToshioFuchigamiI.INTRODUCTIONOrganosiliconcompoundsarereadilyavailableandfairlystablecomparedwith