欢迎来到天天文库
浏览记录
ID:44074891
大小:77.28 KB
页数:7页
时间:2019-10-18
《EPA method 8031 ACRYLONITRILE BY GAS CHROMATOGRAPHY》由会员上传分享,免费在线阅读,更多相关内容在行业资料-天天文库。
1、METHOD8031ACRYLONITRILEBYGASCHROMATOGRAPHY1.0SCOPEANDAPPLICATION1.1Method8031isusedtodeterminetheconcentrationofacrylonitrileinwater.Thismethodmayalsobeapplicabletoothermatrices.Thefollowingcompoundcanbedeterminedbythismethod:_________________________________________________________
2、_____________________aCompoundNameCASNo.Acrylonitrile107-13-1______________________________________________________________________________aChemicalAbstractServicesRegistryNumber.1.2TheestimatedquantitationlimitofMethod8031fordeterminingtheconcentrationofacrylonitrileinwaterisapprox
3、imately10µg/L.1.3Thismethodisrestrictedtousebyorunderthesupervisionofanalystsexperiencedintheuseofgaschromatographsandskilledintheinterpretationofgaschromatograms.Eachanalystmustdemonstratetheabilitytogenerateacceptableresultswiththismethod.2.0SUMMARYOFMETHOD2.1Ameasuredsamplevolume
4、ismicro-extractedwithmethyltert-butylether.TheextractisseparatedbygaschromatographyandmeasuredwithaNitrogen/Phosphorusdetector.3.0INTERFERENCES3.1Methodinterferencesmaybecausedbycontaminantsinsolvents,reagents,glassware,andothersampleprocessinghardwarethatleadstodiscreteartifactsand
5、/orelevatedbaselinesingaschromatograms.Allofthesematerialsmustberoutinelydemonstratedtobefreefrominterferencesundertheconditionsoftheanalysisbyrunninglaboratoryreagentblanks.3.2Samplescanbecontaminatedbydiffusionofvolatileorganicsaroundtheseptumsealintothesampleduringhandlingandstor
6、age.Afieldblankshouldbepreparedfromorganic-freereagentwaterandcarriedthroughthesamplingandsamplehandlingprotocoltoserveasacheckonsuchcontamination.3.3Contaminationbycarryovercanoccurwheneverhigh-concentrationandlow-concentrationsamplesaresequentiallyanalyzed.Toreducecarryover,theCD-
7、ROM8031-1Revision0September1994samplesyringemustberinsedoutbetweensampleswithsolvent.Wheneveranunusuallyconcentratedsampleisencountered,itshouldbefollowedbytheanalysisofsolventtocheckforcrosscontamination.4.0APPARATUSANDMATERIALS4.1Gaschromatographsystem4.1.1Gaschromatograph,analyti
8、calsystemcompletewi
此文档下载收益归作者所有