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1、浅谈绿色化学化工的发展摘要：对绿色化学化工的定义、原则、绿色度的定量化以及绿色化学研究中出现的“绿色非绿”等基本问题的发展及研究进展进行了综述。在此基础上，对绿色化学的基本原则是否需要做必要的补充、绿色化学是否应该单独成为一门学科，以及如何更加有效地定量描述和评价产品的绿色度(绿色化学)和制造过程的绿色度(绿色化工)等基本问题进行了探索和研究。研究结果认为：绿色化学的十二原则仍然是今后绿色化学化工研究的指导原则，但应增加设计并制备可回收并反复使用的物质，如催化剂、手性试剂等，以及使用过程强化及集成方法，改进原有化工工艺，以
2、提高生产效率和减少能耗等两条原则；绿色化学应该成为一门独立的学科而加以深入的研究和发展；绿色化学中的绿色度是可以量化的,但要根据不同的目标选择合适的评价参数和方法；同时要特别注意研究和克服离子液体等绿色化学研究中出现的“绿色非绿”问题。关键词：绿色化学；绿色化学化工；绿色度定量化；绿色非绿DevelopmentandresearchonbasicissuesofgreenchemistryandchemicaltechnologyJIHongbingl,SHEYuanbin2(1SchoolofChemicalEngine
3、ering,SouthChinaUniversityofTechnology,Guangzhou510640,Guangdong,China;2InstituteofGreenChemistryandFfineCchemicals,BeijingUniversityofTechnology,Beijing100022,China)Abstract：Thepaperfirstlyreviewsedthedevelopmentandresearchprogressofnthebasicissues,suchasdefiniti
4、onandprinciplesofgreenchemistryandchemicaltechnologyaswellasquantitativedescriptionofgreennessextendand“non-greenproblems”intheresearchofgreenchemistryandchemicaltechnologyandsecondlyexploresdandstudiesdthequestions,aboveissuesbasedsuchashowtomakeanecessarycomplem
5、entaritiestheopresentbasicprinciples,i.c.,likethetwelveprinciples,whetherthegreenchemistryshouldbeseparatedintoanindependentdisciplineornot,andhowtodescribeandevaluateeffectivelythegreennessextendofgreenproducts(greenchemistry)andgreenprocesses(greenchemicaltechno
6、logy).Intheviewofourpoints,tThetwelveprincipiesareconsideredwouldbestilltheguidingeprinciplestostudygreenchemistryaftertime,buttwonewprinciplescshouldbeadded,thatis,designandmanufactureofmaterialswhichcouldbereclaimedandusedtimeaftertime,suchascatalysts,chiralreag
7、entsetc.et.ahaswellasimprovementofformerchemicalengineeringprocessesandtechniquecsbyusingprocessintensificationandintegrationetc.et.al..Greenchemistryandchemicaltechnologyshouldbeasanindependentdisciplinetobeasthatwecanstudiedinvestigateitmoredeeply.Thegreennessex
8、tendofproductsandprocessescouldbequantitativedescribed,butwemustchoosedifferentparametersandmethodsmustbechosendependingondifferentobjectives・Inthesamet
