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1、AdvancedFreeRadicalReactionsforOrganicSynthesisElsevier,2004Author(s):HideoTogoISBN:978-0-08-044374-4Preface,PageviiListofAbbreviations,Pagesxi-xii1-WhatareFreeRadicals?,Pages1-372-FunctionalGroupConversion,Pages39-563-IntramolecularRadicalCyclizations,Pages57-1214-IntermolecularRadicalAdditionReac
2、tions,Pages123-1565-AlkylationofAromatics,Pages157-1706-IntramolecularHydrogen-AtomAbstraction,Pages171-1857-SyntheticUsesofFreeRadicalsforNucleosidesandSugars:Barton-McCombieReaction,Pages187-1978-BartonDecarboxylationReactionwithN-Hydroxy-2-thiopyridone,Pages199-2139-FreeRadicalReactionswithMetal
3、Hydrides,Pages215-21810-StereochemistryinFreeRadicalReactions,Pages219-23011-FreeRadicalsRelatedtoBiology,Pages231-24612-FreeRadicalsforGreenChemistry,Pages247-256Index,Pages257-258PrefaceThisbookcoversthefundamentalpropertiesoforganicfreeradicalsandtheirsyntheticuses.Itconsistsoftwelvechapters,sta
4、rtingfromfundamentalsandphysicalpropertiesoforganicfreeradicals,reductionandfunctionalgroupconversion,cyclization,addition,alkylationontoaromatics,Bartonreactionandrelatedreactions,Barton-McCombiereaction,Bartondecarboxylation,freeradicalreactionwithmetalhydrides,stereo-selectivefreeradicalreaction
5、s,freeradicalsinbiology,andfreeradicalsforgreenchemistry.Theimportantfactorsinthesefreeradicalreactionsaresomeradicalspecificreactions,asmentionedineachchapter.SincethebasicstudyonfreeradicalreactionshasbeenestablishedbyBarton,Ingold,Stork,Beckwith,Giese,etc.,freeradicalreactionshavebecomeanincreasi
6、nglyimportantandattractivetoolinorganicsynthesis,especiallyinthelasttwodecades.Recently,inadditiontoatypicalbuttoxicradicalreagent,i.e.tributyltinhydride,muchlesstoxicbutmoreeffectiveradicalreagentssuchastris(trimethylsilyl)silane,1,1,2,2-tetraphenyldisilane,samarium(II)iodide,indium,N-acyloxy-2-th
7、iopyridone,triethylborane,etc.havebeendeveloped.Theauthorhopesthatthefreeradicalreactionswillbewidelyappliedtothesynthesisofbiologicallyattractivecompoundswithhighchemoselectivityandstereoselectivity,andgre
