分散液液微萃取-hplc法测定重金属离子的分析

分散液液微萃取-hplc法测定重金属离子的分析

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时间:2019-02-26

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1、AbstractAbstractInrecentyears,peoplehavebeenveryfamiliartotheconceptofenvironmentalpollution,soenvironmentalpollutionpreventionandmanagementalsobecomestheurgent.Amongthese,thepollutionofheavymetalionstotheenvironmentandlifecanbeseeneverywhere,thesewaged

2、ischargesofrefinery,mineminingandheavymetalsinplantsandanimalsthroughthelayersenrichmentinthefoodchain,etc.Thisarticlerepresentedthemethodtodetectthemetalionsinenvironmentalwatersamples,teaanddrugpackagingshellsbycombiningthepreconcentrationofdispersion

3、liquid-liquidmicroextractionandperformanceliquidchromatography(HPLC).Chapter1Severalcommonmethodsfordetectingofmetalionswerereviewedinthischapter.Bysummarizingtheothermethods,wehighlightssomeadvantagesofhighperformanceliquidchromatography(HPLC)method,al

4、sosomeenrichmentmethodscombinatedwithhighperformanceliquidchromatographywererepresented.Chapter2Inthischapter,wehavebuildanewmethodtotesttraceamountsofnickel,cobalt,copperandmercuryinenvironmentliquidbyhighperformanceliquidchromatography(HPLC).Toconcent

5、ratetheionsintheenvironmentalsamplesbyusingdispersiveliquid-liquidmicroextractionasenrichmentmethod,sodiumdiethyldithiocarbamateascomplexingagent,greenextractionagentoflaurylalcoholasextractingagent,thenthesamplewasimpeledintothecolumnthathasfixedratioo

6、fmobilephasefordetection.Inthismethod,therequirementforinstrumentislow,thesensitivityishigh,itissuitableforquantitytargetmetalionsdetectioninwatersamples.Thismethodissuittodetectthetargetheavymetalsinenvironmentalsamplesduetothecelerity,delicacyanlowreq

7、uesttotheapparatus.Chapter3Peoplehavebeendoubtoftheintegrityofthepharmaceuticalindustrybecauseofthetoxicitychromiumcapsules.Chromiumhastwovalencestate,whiletrivalencychromiumisbeneficialtohumanbody,hexavalentchromiumisharmfulelementtohumanbody.Inthischa

8、pter,themethodofcombiningdispersiveliquid-liquidmicroextractionwithhighperformanceliquidchromatography(HPLC)wasusuedfortheseparationanddetectionofdifferentvalenceofchromiumionsinchromiumcapsules.Thismethodachieveddepurposeofsepar

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