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时间:2020-03-20
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1、Unit1MetalsTheuseofmetalshasalwaysbeenakeyfactorinthedevelopmentofthesocialsystemsofman.Oftheroughly100basicelementsofwhichallmatteriscomposed,abouthalfareclassifiedasmetals.Thedistinctionbetweenametalandanonmetalisnotalwaysclear-cut.Themostbasicdefinitioncentersaroundth
2、etypeofbondingexistingbetweentheatomsoftheelement,andaroundthecharacteristicsofcertainoftheelectronsassociatedwiththeseatoms.Inamorepracticalway,however,ametalcanbedefinedasanelementwhichhasaparticularpackageofproperties.Metalsarecrystallinewheninthesolidstateand,withfew
3、exceptions(e.g.mercury),aresolidatambienttemperatures.Theyaregoodconductorsofheatandelectricityandareopaquetolight.Theyusuallyhaveacomparativelyhighdensity.Manymetalsareductile-thatis,theirshapecanbechangedpermanentlybytheapplicationofaforcewithoutbreaking.Theforcesrequi
4、redtocausethisdeformationandthoserequiredtobreakorfractureametalarecomparativelyhigh,although,thefractureforcesisnotnearlyashighaswouldbeexpectedfromsimpleconsiderationoftheforcesrequiredtotearaparttheatomsofthemetal.Oneofthemoresignificantofthesecharacteristicsfromourpo
5、intofviewisthatofcrystallinity.Acrystallinesolidisoneinwhichtheconstituentatomsarelocatedinaregularthree-dimensionalarrayasiftheywerelocatedatthecornersofthesquaresofathree-dimensionalchessboard.Thespacingoftheatomsinthearrayisofthesameorderasthesizeoftheatoms,theactuals
6、pacingbeingacharacteristicoftheparticularmetal.Thedirectionsoftheaxesofthearraydefinetheorientationofthecrystalinspace.Themetalscommonlyusedinengineeringpracticearecomposedofalargenumberofsuchcrystals,calledgrains.Inthemostgeneralcase,thecrystalsofthevariousgrainsarerand
7、omlyorientedinspace.Thegrainsareeverywhereinintimatecontactwithoneanotherandjoinedtogetheronanatomicscale.Theregionatwhichtheyjoinisknownasagrainboundary.Anabsolutelypuremetal(i.e.onecomposedofonlyonetypeofatom)hasneverbeenproduced.Engineerswouldnotbeparticularlyinterest
8、edinsuchametalevenifitweretobeproduced,becauseitwouldbesoftandweak.Themetalsusedcommerciallyinevitablyc
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