羟丙基纤维素接枝改性研究(study on graft modification of hydroxypropyl cellulose)

羟丙基纤维素接枝改性研究(study on graft modification of hydroxypropyl cellulose)

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时间:2018-07-13

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1、羟丙基纤维素接枝改性研究(Studyongraftmodificationofhydroxypropylcellulose)Articlenumber:10044736(2000)04000604StudyongraftmodificationofhydroxypropylcelluloseYangJiamo,LiShirong,YuFaquan,BiYafan,ChenXiaoyan(Departmentofchemicalengineering,WuhanInstituteofchemistry,

2、Hubei,Wuhan430073,China)Abstract:thegraftcopolymerizationofhydroxypropylcellulosewithmethylmethacrylatewascarriedoutbyusingUVandceriumsaltsastwoinitiatorsTheeffectsofreactiontime,temperature,monomerconcentration,photosensitizerorinitiatordosageonthevisc

3、osityoftheproductwereinvestigated.TwokindsofinitiationwerecomparedTheoptimumoperationconditionofthereactionisobtainedKeywords:hydroxypropylcellulose;graftcopolymerization;modification;viscosityCLCnumber:TQ361.6,documentidentifiercode:AReceiveddate:20000

4、509Biography:YangJiamo(1949),male,ProfessorofZhangshuCity,Jiangxi.LongtermteachingandresearchworkinchemicalengineeringandChemicalTechnology0IntroductionThemolecularformulaforcottoncelluloseis(C6H10O5)n,whichisformedThechiefconstituentoftheplantcellmembr

5、ane.CelluloseinthemacromolecularstructureConsistingofrepeatedglucoseunitslinkedtothe1,4betaglycosidicbondThereactioncharacteristicofcelluloseismainlythatitsproductisinhomogeneousSexandcomplexity,themolecularstructureoftherawmaterialhasanimpactonthereact

6、ionprocessThereactionactivityisaffectedbytheneighboringfunctionalgroupandthereactionstripatthesametimeThetypeofreactionisrelatedtothereactionStepprocessingproductstomeetthequalityrequirementsofusersmoredifficult,bigManyofthemneedtoberemodifiedtoimprovet

7、heirperformanceGraftcopolymerizationisoneofthemostcommonandhasbeenprovedbypracticeThemodificationmethodwithremarkableeffectisthroughtwokindsofmacromolecularbackboneChemicallylinkedwithabranchedchaintoproduceaproductWiththecomprehensivepropertiesoftheset

8、womolecules,idealresultscanbeobtainedImproveitsphysicalandchemicalpropertiesoruseperformanceThenewproductcanbesynthesizedbythefollowingwaysThepurposeofimprovingitsqualityorperformance:(1)introducingactivegroupsonmacromolecularbac

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