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1、Developmentofthemetathesismethodinorganicsynthesis——TheNobelPrizeinChemistry2005MoFanyangApril23th,2006TheGroupofZZMNobelPrizesforsyntheticmethodologiesYearLaureatesContributions1912VictorGrignardPaulSabatierforthediscoveryoftheso-calledGrignardreagen
2、t1950OttoPaulHermannDielsKurtAlderfortheirdiscoveryanddevelopmentofthedienesynthesis1979HerbertC.BrownGeorgWittigPhosphorusylide2001WilliamS.KnowlesRyojiNoyoriK.BarrySharplessChirallycatalysedhydrogenationChirallycatalysedoxidation2005YvesChauvinRober
3、tH.GrubbsRichardR.SchrockDevelopmentofthemetathesismethod1912NobelPrizesforsyntheticmethodologiesVictorGrignard1/2oftheprizeFranceNancyUniversityNancy,Franceb.1871d.1935PaulSabatier1/2oftheprizeFranceToulouseUniversity Toulouse,Franceb.1854 d.19411950
4、NobelPrizesforsyntheticmethodologiesOttoPaulHermannDiels1/2oftheprizeFederalRepublicofGermanyKielUniversity Kiel,FederalRepublicofGermanyb.1876 d.1954KurtAlder1/2oftheprizeFederalRepublicofGermanyCologneUniversity Cologne,FederalRepublicofGermanyb.190
5、2 d.19581979NobelPrizesforsyntheticmethodologiesHerbertC.Brown1/2oftheprizeUSAPurdueUniversity WestLafayette,IN,USAb.1912 (inLondon,UnitedKingdom) d.2004GeorgWittig1/2oftheprizeFederalRepublicofGermanyUniversityofHeidelbergHeidelberg,FederalRepublicof
6、Germanyb.1897 d.19872001NobelPrizesforsyntheticmethodologiesWilliamS.Knowles1/4oftheprizeUSASt.Louis,MO,USAb.1917RyojiNoyori1/4oftheprizeJapanNagoyaUniversity Nagoya,Japanb.1938K.BarrySharpless1/2oftheprizeUSATheScrippsResearchInstitute LaJolla,CA,USA
7、b.1941"forthedevelopmentofthemetathesismethodinorganicsynthesis"TheNobelPrizeinChemistry2005YvesChauvin1/3oftheprizeFranceInstitutFrançaisduPétrole Rueil-Malmaison, Franceb.1930RobertH.Grubbs1/3oftheprizeUSACaliforniaInstituteofTechnology(Caltech)Pasa
8、dena,CA,USAb.1942RichardR.Schrock1/3oftheprizeUSAMassachusettsInstituteofTechnology(MIT)Cambridge,MA,USAb.1945IntroductionWhatismetathesis?metameanschangethesismeanspositionScheme1InshortAB+CD→AC+BDNobelPrizeinChemistry2005AVarietyofOlefinMeta
