等规聚丙烯微注塑制品结晶形态和制品收缩的-研究

等规聚丙烯微注塑制品结晶形态和制品收缩的-研究

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大小:3.13 MB

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时间:2019-03-03

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1、ABSTRACTWiththedevelopmentofscienceandtechnology,micro—electromechanicalsystems(MEMS)andmicro—systemstechnology(MST)havebeensuccessivelyappliedtomanyfields.Micro-injectionmolding(MIM)isoneofthemostimportantprocessesforreplicatingmicrostructuredpartsandmicropartswithhighprecision.Becauseoftheapp

2、licationinhigh—grade,precisionandadvancedfieldsofmicroinjectionmoldedparts,thehigherpropertyofthepartsisdemand.Themorphologyofstructureplaysamajorroleinmasteringthefinalpropertiesoftheproducts,therefore,investigationofmorphologyofthemicropartshasimportantsignificance.Inthiswork,theiPPmicroparts

3、withtwodifferentthicknesswerechoseninthestudy.TheinfluenceofprocessingparametersonmorphologyandshrinkageoftwokindsofmicropartsWasinvestigatedbasedonthemicroinjectionmoldingexperiments。Theworkincludes:1.Theinfluenceofscaleeffectonmorphologyofthemicroparts.Bymeansofpolarizedlightmicroscopy(PLM)an

4、dwideangleX—raydiffraction(WAXD),themorphologyevolutionofmicropartswasinvestigated.PLMobservationsindicatedthatmorphologyalongthethicknessdirectionofmicropartsexhibitedasimilarskin—corestructureasmorphologyofthetraditionalinjectionparts.Therearethreestructuresinthemicropartsincludingskinfrozenl

5、ayer,shearlayerandcorelayer,andshearlayerpresentedalargefractionofthethicknessinmicroinjectionmoldedparts.Thecorelayerinthetraditionalinjectionpartspresentedalargefraction.There’Shardlyany13-crystalintwokindsofmicroparts.Thedegreeofcrystallinityofthemicropartsisdifferentatdifferentlocation.Thed

6、egreeoforientationinmicropartwiththicknessof0.5mmishigherthatmicropartswiththicknessof1.0mm.2.Theinfluenceofinjectionspeedonmorphologyofmicroparts.Bymeansofpolarizedlightmicroscopy(PLM)andwideangleX-raydiffraction(WAXD),theinfluenceoftheinjectionspeedonmorphologyevolutionofmicropartswasinvestig

7、ated.Theresultsshowthattwokindsofmicropartsexhibitedthesimilarskin—corestructureatlowinjectionspeed.Withtheinjectionspeedincreasing,theIIIABSTRACTfractionofshearlayerhaslittlechange.Themicropartsexhibitaspecificcore—freemorphology

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