035. Inorganic Chemistry (1973)

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1、TheChemistryofPhosphineProf.Dr.EkkehardFluckInstitutfiJrAnorganischeChemicderUniversit~tStuttgart*ContentsI.Introduction.....................3II.PropertiesofPhosphineanditsDetermination........31.PhysicalPropertiesandData..............32.ToxicityofPhosphine................173.Dete

2、rminationofPhosphine..............17III.PreparationofPhosphine................17PreparationofPhosphinebytheHydrolysisofAluminiumPhosphide......................20IV.ReactionsofPhosphine.................211.ThermalDecomposition,ReactionwithOxygen,ReducingPro-perties.................

3、.....212.TheQuestionoftheExistenceofPhosphineOxideOPH3233.ReactionswithAtomicHydrogenandNitrogen......264.TheSystemsPhosphine/Water,Phosphine/Water/Ammonia,andPhosphine/Water[Ammonia[Methane..........265.ReactionswithAlkaliandAlkalineEarthMetals......276.ReactionswithHalogensandCh

4、loramines........28*ThepresentarticleisarevisedandextendedversionoftheworkpreviouslypublishedbyFluckandNovobilsky:Fortschr.chem.Forsch.13,125(1969).Itisespeciallycon-cernedwiththemanynewphysico-chemicalinvestigationswhichhavebeencarriedoutonphosphine.Theliteraturehasbeencoveredtot

5、heendof1971andinsomecasesbeyondthisdate.E.Fluck7.ReactionswithSodiumHypochlorite..........298.ReactionswithHydrogenHalides............309.ReactionswithMetalandNon-MetalHalides........3010.ReactionswithDiboraneandMonobromodiborane.....3311.ReactionswithSilanesandAlkaliAluminiumhydr

6、ides....3612.ReactionswithHeavyMetalsandtheirIons........3813.ReactionswithAldehydes...............39a)AliphaticAldehydes................39b)AromaticAldehydes................4114.ReactionswithKetones................4215.ReactionswithOlefins................4516.ReactionswithIsocyan

7、ates..............4817.ReactionswithAromaticAcidChlorides.........4818.ReactionswithTrimethylindium............4819.PhosphineasLigandinCoordinationCompounds......49VoDiphosphineandHigherPhosphines............51VI.Literature......................532TheChemistryofPhosphineI.Introduc

8、tionSincethediscoveryofphosphineb