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时间:2020-03-25
《短碳纤维增强尼龙6复合材料的制备与研究.pdf》由会员上传分享,免费在线阅读,更多相关内容在行业资料-天天文库。
1、第10卷第2期2010年1月科学技术与工程Vo1.10No.2Jan.2010l67l—l815(2010)2-0546-04ScienceTechnologyandEngineering⑥2010Sci.Tech.Engng.化工技术短碳纤维增强尼龙6复合材料的制备与研究李春华宋国君杨淑静杨超孙伟(青岛大学高分子材料研究所,青岛266071)摘要碳纤维复合材料是通过双螺杆反应挤出机复合制备,研究了复合材料的微结构和力学性能,碳纤维的扫描电镜照片显示,处理后的碳纤维较未处理碳纤维有更好的表面粗糙度。复合材料断面
2、照片显示处理后的碳纤维和基体尼龙6材料有着很好的界面结合。复合材料的力学性能得到提高,其拉伸强度和拉伸模量分别提高了33%和50%。关键词碳纤维双螺杆挤出硝酸氧化界面结合中图法分类号TQ327;文献标志码Areacteasilywithmatrices,andincreasethesurfaceen—Nylonisthemostpopularengineeringplasticsjustinvirtueoftheattractiveproperties.Carbonfiber—rein‘ergy.Theoxid
3、ationmethodsusedforcarbonfibersur-facesincludeoxidationinvariousplasma【3l4]gas—phaseforcedcomposite(CFRP)isakindofhighperformance,materialusedinhigh—technologyfields,suchastheoxidation[,.anodizati0n[7]。electrochemicaloxida-aerosDaeeandautomobileindustries,as
4、wellasintioninvariouselectrolytes[10’¨,gamma—rayorneutronsportinggoods.Shoacarbonfiber—reinforcedpolymerradion㈦andwetcheroicalmethods【l3】suchasboilingexpandstheapplicationinvariousengineeringfieldtoinsulfuricacid,phosphoricacid,ornitricacid,etc.formaveryimpo
5、rtantclassoftribo—materials.DespiteInthestudy.inordertomanufzlctureCFRPcon—itslowermechanicalpropertiesincomparisonwithcon‘tinuously,CFRPwerepreparedbytwinscrewextru。tinuousfiber.reinforcedpolymers,shortcarbonfiber—der.Weresearchintotheeffectofnitricacidonth
6、eCFreinforcedthermoplasticsisveryattractiveowingtobySEMphotographandtheeffectofCFoncrystalliza—theiradvantagesofeasyfabrication,economyandbet—tionperformanceofCFRPbyDSCcurve.termechanicalpropertiescomparedwithpurepoly[1,21mers.1ExperimentalFiber.matrixadhesi
7、onisveryimportantforme’chanicalpropertiesofCFRP.Itiswellacceptedthat1.1MaterialstheadhesioncanbeenhancedbysurfzLcetreatmentofNylon6resin(PA6)issuppliedbytheChinaPet-carbonfiber.Inordertoachievethepurpose,lotsofrochemicalBaLingCompanyLtd.Thecarbonfibermethods
8、havebeendeveloped,suchasoxidation,coat—(CF)issuppliedbyGuangweiCompanyLtd.ing,andgraftingreaction.Generally,oxidationisa1.2PreparationofCFbettermethodoftreatment.ItmayetchfibersurfalcesCFiscutto
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