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1、導電性核殼型高分子材料的合成、導電性核殼型高分子材料的合成、分析與應用分析與應用王立義國立台灣大學凝態科學研究中心講講題題大大綱綱¢導電性高分子簡介導電性高分子簡介¢導電性高分子之應用介紹導電性高分子之應用介紹¢核殼型導電高分子之結構與特性核殼型導電高分子之結構與特性¢可撓式透明導電電極可撓式透明導電電極¢製備與分析技術製備與分析技術PlasticsPlastics—Pliability—Lightweightstrength—Cheapcostofproduction—Goodelectricalinsula
2、tionInsulatorinelectricitycableInsulatorinelectricitycableHidekiShirakawa(HidekiShirakawa(日本筑波大學材料學院日本筑波大學材料學院))Ziegler-NattaAcetylenePolyacetyleneTacticity-Control100-foldexcessoftheZiegler-Nattacatalyst(Bymistake)Silverytrans-polyacetylenefilm(Notaconducto
3、r)Coppercoloured10-10~10-9Scm-1cis-PolyacetylenetolueneTi(Obu)4CCEtAl3Acetylenen-hexadecanetrans-PolyacetyleneSilvercoloured10-5~10-4Scm-1T.Ito,H.ShirakawaandS.Ikeda,J.Polym.Sci.,Polym.Chem.Ed.12,11-20(1974)AlanAlanMacDiarmidMacDiarmid,Alan,AlanHeegerHeegerE
4、xplosiveinorganicpolymer:Explosiveinorganicpolymer:Poly(sulphurPoly(sulphurnitride)nitride)MetalMetal--LikeLikeSemiconductoratlowSemiconductoratlow--TTAg、Cu~106S/cmPolyacetylenePolyacetyleneTeflon.~10-16S/cm+.+IorAsF(oxidation)103S/cm2510-6S/cmLi(reduction).
5、.Phys.Rev.Lett.,39,1098(1977)The2000NobelPrizeinChemistryThe2000NobelPrizeinChemistryTheRoyalSwedishAcademyofScienceshasdecidedtoawardtheNobelPrizeinChemistryfor2000jointlytoAlanJ.HeegerUniversityofCaliforniaatSantaBarbara,USA,AlanG.MacDiarmidUniversityofPen
6、nsylvania,Philadelphia,USA,HidekiShirakawaUniversityofTsukuba,Japan"forthediscoveryanddevelopmentofconductivepolymers"forthediscoveryanddevelopmentofconductivepolymersAdvantagesAdvantagesòLightweightòFlexibleòEasyProcessòCheapòVersatileExamplesofcurrentlywid
7、elyusedtypesofExamplesofcurrentlywidelyusedtypesofconductingpolymersconductingpolymersConductivityofvariousmetallic,semiconductor,Conductivityofvariousmetallic,semiconductor,andinsultingmaterialsandinsultingmaterialsConductivitiesofconductingpolymersvarywide
8、lyConductivitiesofconductingpolymersvarywidelyPotentialIndustrialApplicationsforPotentialIndustrialApplicationsforConductingPolymersConductingPolymersòAntistaticCoatingsòCableShieldingòElectrode
