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《VO(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ)和Cu(Ⅱ)的2,3-二(3,5-二甲基-1H-吡唑基)喹啉配合物的合成与表征.pdf》由会员上传分享，免费在线阅读，更多相关内容在行业资料-天天文库。
1、第28卷第6期无机化学学报Vo1．28No．62012年6月CHINESEJOURNAlLOFINORG,NICCHEMISTRY1245—1250vo(D,，Fe(D，Co(n)，Ni'(Ⅱ)和Cu(1I)的2，3--(3，5·二甲基．1H,．吡唑基)喹啉配合物的合成与表征SandhyaRaniD。AnanthaLakshmiPVKamalaPrasadVJayatyagaRajuV’4(。DepmofChemistry,UniversityCollegeof&ience,OsmaniaUniversity,Hyderabad-500007，Andhr
2、a~adesh．India．1(~DeniscoChemicalsPrivateLimited,Plo~#D-24，．Phase一IDA，JeedimetlaHyderabad．-500055，AndhraPradesh,India．)~DepartmentofChemistry,UniversityCollegeforWomen,OsmaniaUniversity,Koti，Hyderabad．500001，AndhraPradesh，Indio．)(4DepartementofChemistry,TheUniversityofDodoma,P．O．b
3、oxNumber259．Dodoma,Tanazania)摘要：合成了vo(I)，Fe(Ⅱ)，Co(I)，Ni(Ⅱ)和Cu(Ⅱ)的2，3一-0，5．二甲基．1H-．吡唑基)喹啉配合物(BDMPQ)并用元素分析、电导、热分析、光谱和顺磁共振等技术对其表征。结果表明所有配合物均为八面体构型。BDMPQ起中性双二齿NN供体的作用并形成多核配合物。关键词：金属配合物；2，3一-(3，5一二甲基．1吡唑基)喹啉；NN供体；多核配合物中图分类号：0614．4文献标识码：A文章编号：1001．4861(2012)06．1245．-06SynthesisandChara
4、cterizationofvo(D,，Fe(II)，,Co(II),，Ni(DandCu(H)Complexesof2，3-Bis(3，5-dimethy1．-1H,-pyrazol·1-y1)QuinoxalineSandhyaRaniD。AnanthaLakshmiPV，'KamalaPrasadV。JayatyagaRajuV(DepartmentofChemistry,UniversityCollegeofScience，Osmanh~University,Hyderabad．500007，,AndhraPradesh．InCa．)，(~Deni
5、scoChemicalsPrivateLimited,Plot#D一24，Phase一IDA，JeedimetlaHyderabad．-500055，AndhraPradesh，．India．)~DepartmentofChemistry,UniversityCollegeforWomen,OsmaniaUniversity,Koti,Hyderabad-500001，AndhraPradesh,India．)(4DepartementofChemistry,TheUniversityofDodoma,P．O．boxNumber259，．Dodoma,T
6、anazania)Abstract：vo(n)，Fe(Ⅱ)，Co(Ⅱ)，Ni(11)andCu(Ⅱ)comolexesof2，3-his(dimethy1．1H．pyrazo1．1一y1)quin~：ahnelIBDMPQI)havebeensynthesizedandcharacterizedbyelementalanalysis，conductance，therma1．，spectralandESRtechniques．Octahedralgeometrieshavebeenproposedforallthecomplexes．BDMPQactsas
7、aneutralhis．bidentateNNdonorandformspolynuclearcomplexes．Keywords：metalcomplexes；2，3-bis(dimethyl一1口--pyrazol一1一y1)quinoxaline，NNdonor．，polynuelearQuinoxalinesareanimportantclassofnitrogen．applicabilities．containingheterocycleswithavarietyofbiologicalPyrazoleanditssyntheticanalog
8、uesexhibitactivities，specificallyasAMPMG
