《药物合成反应》人名反应.doc

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1、《药物合成反应》人名反应授课教师：武汉大学药学院郭鹏教授2010,12,201.Aldolcondensation2.Arndt–Eisterthomologation3.Baeyer–Villigeroxidation4.Beckmannrearrangement5.Benzilicacidrearrangement1.Benzoincondensation2.Birchreduction3.Buchwald–Hartwigamination4.Cannizzaroreaction5.Claisencondensation1.Claisenrearrangem

2、ent2.para-Claisenrearrangement3.Clemmensenreduction4.Coperearrangement5.Criegeemechanismofozonolysis1.Curtiusrearrangement2.Darzenscondensation3.Delépineaminesynthesis1.Demjanovrearrangement2.Tiffeneau–Demjanovrearrangement3.Dieckmanncondensation4.Favorskiirearrangement1.Friesrearran

3、gement2.Gabrielsynthesis3.Gattermann–Kochreaction4.Hofmannrearrangement5.Houben−Hoeschreaction6.Jonesoxidation1.Knoevenagelcondensation2.Leuckart–Wallachreaction3.Mannichreaction4.Meerwein–Ponndorf–Verleyreduction5.Michaeladdition1.Moffattoxidation2.Nefreaction3.Oppenaueroxidation4.P

4、aal–Knorrfuransynthesis1.Paal–Knorrpyrrolesynthesis2.Perkinreaction3.Pinacolrearrangement基团迁移顺序：富电子基团迁移最快烷基：3o>环己基>2o>苄基>苯基>1o>甲基>H取代芳基：给电子取代的迁移能力大于无取代的芳基，无取代大于吸电子基团取代的芳基4.Prévosttrans-dihydroxylation1.Prinsreaction2.Reformatskyreaction3.Reimer–Tiemannreaction4.Robinsonannulations1.R

5、obinson−Schöpfreaction2.Rosenmundreduction3.Sandmeyerreaction1.Schmidtrearrangement2.Sommeletreaction3.Sommelet–Hauserrearrangement1.Stobbecondensation2.Streckeraminoacidsynthesis3.Swernoxidation1.Vilsmeier−Haackreaction2.[1,2]-Wittigrearrangement3.[2,3]-Wittigrearrangement4.Wolffrea

6、rrangement5.Wolff–Kishnerreduction1.Woodwardcis-dihydroxylation有关Cr的氧化剂极性反转