绿色热致相分离法制备pvdf平板膜

绿色热致相分离法制备pvdf平板膜

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时间:2019-01-30

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1、万方数据AbstractPoly(vinylidenefluoride)(PVDF)hasbeenwidelyusedinmicrofiltration,ultrafiltration,membranebioreactors,membranedistillation,gasseparation,pollutantremovalfromwater,recoveryofbiofuels,separationforlithiumionba:ttedesandionexchangeprocessesduetoitsoutstandi

2、ngproperties,suchashighthermalstability,goodchemicalresistanceandmembraneformingproperties.ThePVDFmembranesincludingsheets,hollowfibersandtubes,Canbefabricatedbyimmersionprecipitationandthermallyinducedphaseseparation.Recently,thePVDFmembraneshasbeendevelopedrapidl

3、yinourcountryandlotsofeconomicandsocialbenefitshavebeenobtained.SolargeamountsoforganicsolventshavebeenproducedtopreparePVDFmembranesviaNIPSorTIPS.Unfortunately,environmentalpollutionandraw-materialwastes,areobviousandurgentissuesduetothedifficultlyinrecyclingorgan

4、icsolvents.Recently,theuseofionicliquidsOLs)asaclassofgreensolventshasbecome谢delypopularasareplacementfortheconventionalvolatilesolvents,whichareenvironmentalpollutantsoreventoxic.ILshaveplentyofuniqueandinterestingproperties,suchastheirnegligiblevaporpressure.They

5、arealsonon-flammable,non-explosive,haveexcellentchemicalandthermalstability,excellentsolventpropertiesandhighionicconductivity。Moreover,theyCanberecycledandCallreduceenvironmentalpollutioninthisrespect.PVDFmembraneswillbepreparedbythermallyinducedphasetechnologywhi

6、chtakesPVDFasmembranematerialandusesionicliquidstoreplaceorganicsolventasdiluentsinthisstudy.ThemembraneformationmechanismofthermalinducedphasemeltprocessforpreparationofPVDFmembranewillberesearched,andthemembranemicroporousstmcturedesign,construction,reorganizatio

7、nandoptimizationmechanismwillbeexploredinthemembranemakingprocess.Furthermore,ionicliquidsWaseffectivelyrecoveredbyAtmosphericdistillation.ThemembraneformationmechanismofgreenthermallyinducedphasemeltmembranetechnologywimionicliquidsasdiluentsforpreparationofPVDFme

8、mbranewillbestudiedinordertoprovidetheoreticalbasisandtechnicalsupportforpreparationofhighperformancepolymermembrane.Thediluents1-butyl-1-methylp

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