清洁催化氧化环己烯合成己二酸的.研究

《清洁催化氧化环己烯合成己二酸的.研究》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

1、郑州大学硕士学位论文AseriesofProPertiesofeatalystwereeharaeterizedbythermalanalysisteehniquesandmulti一PointBETadsorption一desorptionPrineiPle.TheresultsoftlzeDSCandtheDTGeurvesshowthattheeatalysthashigherthermalstability.1’henitrogenadsorption一desorptionisothermofthePW/SBAeatalystwasmensurated.Thesur几ee

2、area。featalyst15367.1时·9.’，porevo一umev15o.Zem3·g一’andporesizeR151.089nm.ThestandardeombustionenthalPyofadiPieaeidwasdeterminedbyXR丫ICealorimeter，汕ieh15一Zsol.ou·mol一1at山estandardeondition.Thereli汕ilityofinstrument15testedbyehemicalagentnaPhthalene，the汕soluteerm:155.6kJ·mol一’andtherelativeerror

3、150.109%fortheeomParisonbetweenthesetimatedvalueand1iteraturevalueaboutthestandardcombustionenthalPyofnaPhthalene.Aeeol·dingtothethermodynamierelationshiP，thestandardformationenthalPyofadiPieaeidwascaleu一atedtobe一959.32kJ·mol一1.ThemeltingpointandthemeltingenthalpyweredeterminedbyDTA一TGAforadi

4、picacid，whiehare152.5oCand一ZsZoJ·g一I，reSPectively.Keywords:adiPieaeid;eyelohexene:SBA一15;sPeeificsurfaeearea;thermodynamiePr0Pertles111郑州大学硕士学位论文目录摘要.........................................................................................................................……ABSTRACT.............

5、................................................................................................……111目录.....................……，..............................……，................……，.................................……第一章绪论..........................................................................

6、....................................……1.1己二酸的物化性质...................................................................……，......……，…、..…11.2己二酸的用途.............................................……，..............................................……11.3己二酸的工业生产方法........................................

7、..........................................……21.3.1苯酚法...........................................................................……，...................……21.3.2环己烷空气氧化法............................................································